PBS
Pbs: Napoleon, the Man and the Myth
Part of a larger site on the Napoleonic Era this page and its links describe Napoleon the man including his early years.
Other
The Napoleon Series
This site is dedicated to research and scholarship on the age of Napoleon Bonaparte and provides links to articles on the military history of that time.
Other
Napoleonic Guide
Ambitious effort to cover the French Revolution and the life of Napoleon Bonaparte. Site contains an impressive amount of information, key terms, books, images. etc.